Was listening to one of my chillout stations on Last.fm and came across a great track by Thunderball named "On the Sly" from their "Scorpion Rising" album.
Checking out their Myspace page, it seems like they enjoy putting some great bossa themes in their music. Just the name Thunderball conjures up images of James Bond and the 1965 classic movie and this music is a great replica of the music from that time.
If this music were for a spy film soundtrack, "On the Sly" would be the moment where the superspy has his encounter with a sexy adversary. The track is built around two echoing synth melodies with some bluesy electric guitar mixed in. It vaguely reminded me a bit of the Lethal Weapon soundtrack when I heard this one.
"Chicachiquita" featuring Miss Johnna is a light bossa-flavored track with a great groove and features a jazz flute intertwined with some electronic sounds and a soft guitar in the background.
"Thunder in the Jungle" begins with the sound of a driving storm broken in by some funky guitar and scathing trumpet hits. These guys specialize in chillin', in my opinion, but this is a great upbeat dance track.
"The Road to Benares" was the first one to play on their MySpace page for me and immediately reminded me of David Holmes' work on Ocean's Twelve. It has a great percussive beat with middle eastern sitar and other strings throughout. Again it brought to mind the spy movie where our hero descends upon Morocco to chase the world-class criminal.
If you're looking for some great atmospheric chillout music, check out the cinescapes of Thunderball!